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Research Paper | Synapse

May 15, 2026

LDH-mediated interfacial redox formation of phyllomanganate from KMnO₄: mechanistic insights and subsequent fluorination pathways

ARAbderraouf RouagCentre National de la Recherche Scientifique SHSarah HennequartCentre National de la Recherche Scientifique RPregis porhielCentre National de la Recherche Scientifique

Key Points

This research investigates the mechanisms by which layered double hydroxides facilitate redox reactions with potassium permanganate to form phyllomanganate.
Utilized layered double hydroxides with 3d metal cations (Co²⁺, Cu²⁺, Fe³⁺) contacted with potassium permanganate solution.
Analyzed the resulting chemical composition and formation pathways under various conditions.
Demonstrated successful formation of phyllomanganate through interfacial redox reactions.
Identified distinct fluorination pathways following the redox process.

Abstract

Thanks to their versatile chemical composition, layered double hydroxides (LDH) containing only 3d ions as intralamellar cations (Co²⁺, Cu²⁺, and Fe³⁺), when contacted with a potassium permanganate solution, lead to...

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Cite This Study

Rouag et al. (Thu,) studied this question.

synapsesocial.com/papers/6a06b81ce7dec685947aa9ae https://doi.org/https://doi.org/10.1039/d6dt00203j