This research explores how isomerization of PBDF affects the properties of its structural isomer PCCD.
Isomerization of poly(benzodifurandione) was performed through ring opening.
Comparative analysis of properties between poly(benzodifurandione) and poly(chromenochromenedione).
Isomerization successfully creates poly(chromenochromenedione) from poly(benzodifurandione).
Variations in backbone topology led to significant differences in n-type polymer properties.
Abstract
Isomerization of poly(benzodifurandione) (PBDF) via ring opening yields poly(chromenochromenedione) (PCCD), demonstrating how variations in backbone topology can affect n-type polymer properties.