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测量了从Si (100)和Si (111)表面解吸的D₂的平动能,发现其大致等于表面温度Tₒ下的热期望值。将这些结果与先前测量的内部状态分布相结合,解吸分子的总能量大约等于Tₒ下的平衡期望值。因此,表明存在较大能垒的吸附实验与表现出微不足道吸附能垒的解吸实验存在分歧,该系统中细致平衡的适用性需要重新检验。
Kołasiński et al. (Mon,) 研究了这一问题。
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