Stereochemical control and its consequences in VO(acac) 2 complexes: an integrated study of trans / cis isomerism with quinoline and isoquinoline

Key Points

• Characterize the stereochemistry of new VO(acac)2 adducts with quinoline and isoquinoline forms.
• Combined experimental and theoretical approaches
• Characterization of three novel adducts: VO(acac)2 (trans-quinoline), VO(acac)2 (trans-isoquinoline), VO(acac)2 (cis-isoquinoline)
• Successful characterization of three adducts with distinct isomeric forms
• Demonstrated stereochemical variations and their implications in the complexes