Key points are not available for this paper at this time.
Clumps of narrowly spaced lines (∼10 lines per cm−1 in a 2 cm−1 wide clump) appear in the stimulated emission pumping spectrum of the acetylene X̃ 1∑g+ state near 27 900 cm−1 of vibrational excitation above the vibrationless level. All of the lines in a given clump arise from transitions into levels with the same lower state J″ value. Thus, the fine structure within each clump is of a purely vibrational nature. Rotationally resolved and assigned spectra at such high vibrational excitation have not been previously reported for a polyatomic molecule. The unique qualities of these spectra make it possible for the first time to apply one of the suggested criteria of quantum chaos to a real molecular spectrum. Analysis of the spacings between adjacent lines in several of these clumps shows that they approximately follow a Wigner distribution rather than a Poisson distribution, a characteristic which is expected for chaotic behavior within the molecule.
Abramson et al. (Thu,) studied this question.