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Benefiting from their low price, high performance stability, and moderate-to-high detection sensitivity, surface-enhanced Raman scattering (SERS) substrates made of noble metal-free materials have received much attention in the past few years. Improving the SERS sensitivity of non-noble metal materials is of great significance. Here, we propose a strategy of combining ultrathin graphene oxide (GO) sheets with plasmonic non-noble metal materials to enhance SERS sensitivity. By leveraging the adsorption property of GO and plasmonic hotspots of MoO2 nanoparticles (MoO2-NPs), the enrichment of target molecules around hotspots can be realized, thereby achieving high detection sensitivity. Highly surface-roughened plasmonic MoO2 nanospheres are wrapped by ultrathin-GO sheets, forming an ultrathin-GO/MoO2-NP hybrid. GO sheets with a huge specific surface area and high adsorption ability can trap analyte molecules in the locations near or in hotspots of MoO2-NPs. A uniform film of ultrathin-GO-wrapped MoO2-NPs shows a high enhancement factor of ∼1.12 × 108 and good spectral homogeneity (relative standard deviation, RSD = 9.7%). The detectable concentration limit for rhodamine 6G molecules is ∼10 pM, demonstrating high SERS sensitivity. In addition, the ultrathin-GO/MoO2-NP hybrid also exhibits excellent structural and chemical stabilities. The fabricated GO/MoO2-NP hybrid has promising applications in the SERS-based detection of trace chemical molecules.
Li et al. (Fri,) studied this question.