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Abstract The choice of appropriate materials is of paramount importance in realizing a high efficiency perovskite solar cell. Lead free eco‐friendly perovskite solar cell architecture is theoretically investigated using solar cell capacitance simulator (SCAPS) for device performance. Preliminary investigations on Cs 2 SnI 6 solar cell architectures have indicated that the presence of hole transport layer is crucial in achieving an open‐circuit voltage greater than 0.6 V. The presence of a valence band offset between the Cs 2 SnI 6 absorber and hole transport layer has a significant detrimental impact on the short‐circuit current density and fill factor of the cell. A novel device architecture employing TiO 2 as an electron transport material and Cu 2 O as a hole transport material is proposed to overcome the limitations associated with the current designs. Theoretical investigations are carried out employing 1D SCAPS simulation program in order to optimize the structure by varying the perovskite thickness, bandgap, and defect concentration. The proposed solar cell after optimization has a practically realizable power conversion efficiency of 17.77%.
Debashish Pal (Thu,) studied this question.