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The adsorption of C 12 E 8 onto a clean air−water interface is studied by using a video-enhanced pendant bubble tensiometry. The controlling mechanism for mass transfer changes as a function of bulk concentration; it shifts from diffusion control at dilute concentration to mixed diffusion−kinetic control at more elevated bulk concentration. The adsorption of C 12 E 8 is found to be anticooperative from the equilibrium surface tension data compared with the prediction of the (generalized) Frumkin model. Relaxation profiles of surface tension for C 12 E 8 molecules absorbing onto a freshly created air−water interface for 21 different bulk concentrations are obtained. Comparison is made for the entire relaxation period of the tension data and the model predictions. Values of the diffusion coefficient and the adsorption/desorption rate constants of C 12 E 8 are calculated from these dynamic surface tension profiles.
Lin et al. (Mon,) studied this question.