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The search for new efficient physisorbents for gas capture and storage is the objective of numerous ongoing researches in the realm of functional framework materials. Here we present the CO 2 and H 2 uptake capacities of nitrogen rich covalent triazine frameworks (CTFs) based on lutidine, pyrimidine, bipyridine, and phenyl units, showing superior gas uptakes and extremely high CO 2 selectivities toward N 2 . The CO 2 uptake of a bipyridine-CTF synthesized at 600 °C (5.58 mmol g –1, 273 K) is the highest reported for all CTFs so far and the second highest for all porous organic polymers (POPs). Moreover, the CO 2 selectivity toward N 2 of a nitrogen-rich pyrimidine-based CTF synthesized at 500 °C (Henry: 189, IAST: 502) is the highest reported for all POPs, and the H 2 uptake of CTF1 synthesized at 600 °C at 1 bar (2.12 wt %, 77 K) is the highest found for all CTFs to date as well. With the wide range of sorption data at hand, we carve out general trends in the gas uptake behavior within the CTF family and nitrogen-containing porous polymers in general, revealing the dominant role of the micropore volume for maximum CO 2 uptake, while we find that the nitrogen content is a secondary effect weakly enhancing the CO 2 uptake. The latter, however, was identified as the main contributor to the high CO 2 /N 2 selectivities found for the CTFs. Furthermore, ambient water vapor sorption has been tested for CTFs for the first time, confirming the highly hydrophilic nature of CTFs with high nitrogen content.
Hug et al. (Wed,) studied this question.