Rechargeable zinc–air batteries (ZABs) are promising candidates for sustainable energy storage; however, their performance is severely limited by sluggish oxygen reduction and evolution (ORR/OER) kinetics. Here, a hard‐templating etching strategy was employed to construct nitrogen‐doped hollow mesoporous carbon spheres embedded with NiCo nanoparticles (NiCo@N‐HMCS). The hollow nanostructure, together with a strong electronic coupling between NiCo alloys and N‐doped carbon, provides abundant accessible active sites, optimized charge transfer, and robust structural stability. As a result, NiCo@N‐HMCS delivers remarkable bifunctional electrocatalytic activity in alkaline media, with a half‐wave potential of 0.84 V for the oxygen reduction reaction and an overpotential of 330 mV at 10 mA cm −2 for the oxygen evolution reaction. When applied in ZABs, the catalyst delivers a high open‐circuit voltage of 1.56 V, a peak power density of 185.53 mW cm −2 , and durable cycling over 300 h. The flexible ZAB configuration also delivers a power density of 79.06 mW cm −2 and stable operation of 120 h. This study demonstrates a robust platinum‐group‐metal‐free strategy for advancing next‐generation rechargeable and flexible energy storage systems.
Tan et al. (Thu,) studied this question.