January 1, 2009

Selective gas adsorption in a microporous metal–organic framework constructed of CoII4 clusters

YCYoung Eun CheonSK Group (South Korea)MSMyunghyun Paik SuhSeoul National University

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Abstract

A porous metal-organic framework, Co(II)(4)(micro-OH(2))(4)(MTB)(2) x (H(2)O)(4)(n) x 13nDMF x 11nH(2)O (SNU-15), has been prepared; the X-ray crystal structure reveals a CaF(2)-like structure that generates 3D channels and the desolvated solid Co(II)(4) (micro-OH(2))(4)(MTB)(2)(n) (SNU-15') exhibits selective gas sorption properties for H(2) and O(2) gases over N(2) at 77 K, with exceptionally high O(2) density, as well as for CO(2) over CH(4) at 195 and 273 K, suggesting its potential application in gas separation processes.

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Cheon et al. (Thu,) studied this question.

synapsesocial.com/papers/69dd4d1127c48be1bb40cba5 https://doi.org/https://doi.org/10.1039/b900085b

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