Investigation of Iridium Catalyst Degradation in PEM Water Electrolyzers: Current Density or Cell Voltage?

Proton exchange membrane (PEM) water electrolyzers represent a cornerstone technology in the sustainable production of green hydrogen. However, their large-scale commercialization is hindered by catalyst degradation, particularly the iridium-based anode, which compromises the efficiency and durability of the stack. This study delves into the degradation mechanism(s) of the Ir-based catalyst in the anode of PEM electrolyzers, focusing on the influence of operating conditions such as current density and cell voltage. We have utilized the state-of-the-art R&D platform “PEMI” at Plug Power to construct a rainbow stack that contains several 50 cm 2 membrane electrode assemblies (MEAs) with different membrane thicknesses. This innovative approach enables identical current densities across different MEAs while varying the cell voltage on the anode catalyst layer, thereby isolating the effect of cell voltage from current on catalyst degradation. Our investigation seeks to clarify the puzzle whether it is the current density or the cell voltage that determines the transition and degradation of iridium-based catalysts. Preliminary results indicate that different oxidation states of Iridium exhibit significantly different kinetics and conductivity at varied cell voltages. This is corroborated by our synchrotron-based in situ X-ray absorption spectroscopy experiments that unraveled evolution of the anode catalyst layer at elevated cell voltages. By systematically analyzing the degradation patterns of MEAs with different membrane thickness under controlled conditions, we pinpointed the operational parameter that drives catalyst degradation. The finding provides in-depth understanding of the underlying principles that govern the iridium-based catalyst durability and points to strategies mitigating the degradation. It will pave the way for more resilient and efficient PEM water electrolyzers. Acknowledgement . This research used beamline 7-BM (QAS) of the National Synchrotron Light Source II, a US Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory Contract DE-SC0012704. Beamline operations were supported in part by the Synchrotron Catalysis Consortium Grant DE-SC0012335. Keywords: PEM water electrolyzers, catalyst degradation, iridium, current density, cell voltage, MEAs.