Palladium-catalyzed conversion produces carboxylic acids from aryl iodides and bromides, indicating efficient carbon sourcing.
Aryl iodides, bromides and vinyl-triflates are usually converted in high to excellent yields into the corresponding carboxylic acids through a parallel palladium-catalyzed hydroxycarbonylation using lithium formate and acetic anhydride as external condensed source of carbon monoxide.
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Iazzetti et al. (2025) studied this question.
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