Experimental study demonstrates direct carbonation of aromatic acids using ethyl bromodifluoroacetate, indicating an efficient catalytic route to monoalkyl phthalates.
A novel and efficient approach for direct carbonation of aromatic acids with ethyl bromodifluoroacetate as the carbonyl source is reported. A broad range of substrates bearing various functional groups were tolerated, leading to monoalkyl phthalate derivatives in moderate to good yields.
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Tao et al. (2019) studied this question.
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