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July 15, 2025

Metal-Organic Framework/Organocatalyst Combinations as Powerful Multicatalytic Systems for Aerobic Oxidations

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Authors

JAJuan Camilo Arango‐DazaStockholm UniversityMOMathieu OnillonStockholm UniversityLNLeonie NorkStockholm University

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Implication

Multicatalytic systems demonstrate high selectivity in aerobic oxidation, suggesting potential for valuable organic compounds.

Key Points

  • Multicatalytic systems utilizing metal-organic frameworks achieve sustainable aerobic oxidation with high selectivity.
  • A Zr-MOF-808 and hydroquinone catalyst enable the oxidation of anilines to azoxybenzenes under mild conditions.
  • Ligand-to-metal charge-transfer generates reactive oxygen species, facilitating aerobic transformations without external stimuli.
  • The approach is versatile, effectively oxidizing thiols to disulfides and benzylamines to coupled products with varying co-catalysts.

Cite This Study

Arango‐Daza et al. (2025) studied this question.

synapsesocial.com/papers/689a02bce6551bb0af8cc614https://doi.org/10.26434/chemrxiv-2025-hwsl2-v2
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Also Consider

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  1. 1Metal‐Organic Framework/Organocatalyst Combinations as Powerful Multicatalytic Systems for Aerobic Oxidations2025
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  3. 3A Review on Metal-Organic Frameworks as Catalytic Material for Oxidation Reactions.2025 · 8 citations
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