Multifunctional Eu(III) and Sm(III) Coordination Polymers Built with Silane-Bridged Dicarboxylate Ligand: Structure, Luminescence and Magnetism

Ana Arauzo; Mirela‐Fernanda Zaltariov; Elena Bartolomé; Sara Fuertes; Radu Tigoianu; Sergiu Shova; Maria Cazacu

doi:10.1039/d5tc02436f

January 1, 2025Journal of Materials Chemistry COpen Access

Multifunctional Eu(III) and Sm(III) Coordination Polymers Built with Silane-Bridged Dicarboxylate Ligand: Structure, Luminescence and Magnetism

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Key Points

Coordination polymers exhibit notable luminescence and magnetism based on their lanthanide composition.
The compounds showcased here include Eu(III) and Sm(III), demonstrating new structural properties from silane-bridged ligands.
Synthesis involved a reaction with bis(p-carboxyphenyl)diphenylsilane, resulting in three distinct coordination structures.
Such unique properties highlight potential applications in materials science and optoelectronics.

Implication

Synthesis of coordination polymers shows luminescence and magnetism in lanthanide compounds, suggesting potential applications.

Abstract

Three novel coordination polymers ‒ [LnLNO3(o-Phen)] (Ln: Eu(III) (1), Sm(III) (2)) and [Eu2L3EtOH(H2O)3]·1.5EtOH·H2O (3) ‒ were synthesized by reacting the respective lanthanide nitrates with the organosilane dicarboxylic acid bis(p-carboxyphenyl)diphenylsilane (H2L)...

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Arauzo et al. (2025) studied this question.

synapsesocial.com/papers/68a368920a429f797332e025 https://doi.org/10.1039/d5tc02436f

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Multifunctional Eu(III) and Sm(III) Coordination Polymers Built with Silane-Bridged Dicarboxylate Ligand: Structure, Luminescence and Magnetism

Key Points

Implication

Abstract

Discussion

Cite This Study

Multifunctional Eu(III) and Sm(III) Coordination Polymers Built with Silane-Bridged Dicarboxylate Ligand: Structure, Luminescence and Magnetism

Key Points

Implication

Abstract

Discussion

Cite This Study

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