Preparation of Bismuth Vanadates with Rich Oxygen Vacancies Using Different Sol pH and Their Photocatalytic Behavior in Degradation of Methylene Blue

Gel precursors were formed by reacting bismuth nitrate pentahydrate, acetic acid, sodium metavanadate, and NaOH. pH was adjusted using NaOH solution followed by calcination to obtain bismuth vanadate (BiVO4) photocatalysts. During synthesis, pH directly influenced the formation and structure of the gel network. Therefore, the effects of pH on the microstructure and photocatalytic activity of BiVO4 were investigated. At pH 3, the sample consisted of microspheres formed by tightly packed small particles. At pH 5, the microspheres transformed into aggregated flakes. Photocatalytic performance was evaluated through methylene blue (MB) degradation, revealing the sample prepared at pH 7 (7-BVO) demonstrated the highest efficiency. The electronic band structure, bandgap, and band edge positions of 7-BVO were probed by density functional theory (DFT) and UV-vis absorption spectra. Furthermore, photoluminescence spectroscopy, electrochemical measurements, active species trapping experiments and liquid chromatography mass spectrometry technique collectively revealed the possible mechanistic pathways for MB photodegradation by 7-BVO.