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August 17, 2025Inorganic Chemistry Frontiers

Magnetically Bistable Co(II) and Fe(II) Complexes Featuring Pentyl-Decorated Pyridyl-Benzimidazole Ligands: Role of Isomerism and Chirality

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Cobalt(II) and iron(II) complexes exhibit magnetically bistable behavior based on ligand variations,
The study reported distinct behaviors among isomers, specifically with pentyl-decorated ligands and distinct substitutions.
The ligands used include bidentate structures featuring pentyl and methylbutyl groups, highlighting structural diversity.
Further understanding of isomerism and chirality in these complexes could enhance applications in magnetic materials.

Implication

Synthesis of magnetically bistable cobalt(II) and iron(II) complexes shows isomerism and chirality impact.

Abstract

Three variants of 2-(pyridine-2-yl)-1H-benzimidazole bidentate ligands, with distinct pentyl substituents (n-pentyl (L1), (2S)-2-methylbutyl (L2S), and (2R)-2-methylbutyl (L2R)), were synthesized and employed to prepare magnetically bistable cobalt(II) and iron(II) complexes. The...

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Cite This Study

Šagátová et al. (2025) studied this question.

synapsesocial.com/papers/68a36ddf0a429f79733312e8 https://doi.org/10.1039/d5qi01269d

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Implication

Synthesis of magnetically bistable cobalt(II) and iron(II) complexes shows isomerism and chirality impact.

Magnetically Bistable Co(II) and Fe(II) Complexes Featuring Pentyl-Decorated Pyridyl-Benzimidazole Ligands: Role of Isomerism and Chirality

Key Points

Implication

Abstract

Discussion

Cite This Study

Magnetically Bistable Co(II) and Fe(II) Complexes Featuring Pentyl-Decorated Pyridyl-Benzimidazole Ligands: Role of Isomerism and Chirality

Key Points

Implication

Abstract

Discussion

Cite This Study

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