4f-intermediate valence in an ytterbium-bipyridine coordination solid

Evgeniia E. Luneva; Frédéric Aribot; Joseph E. McPeak; Kasper S. Pedersen; Maja A. Dunstan; Nathan J. Yutronkie; А. Рогалев; Grégory Nocton

doi:10.1039/d5cc04048e

January 1, 2025Chemical Communications

4f-intermediate valence in an ytterbium-bipyridine coordination solid

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Key Points

Intermediate valence was observed in the newly characterized ytterbium-bipyridine coordination solids.
The study highlights the spectroscopic evidence from decamethylytterbocene complexes with bipyridine linkers.
Characterization involved YbCp*2(bipy) and YbCp*2(Me2bipy), offering insights into their structure and properties.
Understanding these coordination solids may lead to advances in materials science and coordination chemistry.

Implication

Spectroscopic evidence reveals intermediate valence in ytterbium-bipyridine coordination solids, suggesting new properties.

Abstract

We report the first structurally characterised coordination solids based on decamethylytterbocene, using bipyridine linkers to form YbCp*2(bipy) and YbCp*2(Me2bipy). Analogous to their mononuclear cousins known for intermediate valence, spectroscopic evidence...

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Cite This Study

Luneva et al. (2025) studied this question.

synapsesocial.com/papers/68af432fad7bf08b1ead23cd https://doi.org/10.1039/d5cc04048e

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4f-intermediate valence in an ytterbium-bipyridine coordination solid

Key Points

Implication

Abstract

Discussion

Cite This Study

4f-intermediate valence in an ytterbium-bipyridine coordination solid

Key Points

Implication

Abstract

Discussion

Cite This Study

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