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August 19, 2025Angewandte Chemie International Edition

Visible‐Light‐Driven Iron‐Catalyzed Atom Transfer Radical Addition of CH2Br2 to Alkenes: Facile Access to 1,3‐Dibromo Compounds

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Authors

NYNing YanYWYi WangMBMing Bao

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Overview

Atom transfer radical addition using visible-light improves access to 1,3-dibromo compounds, highlighting excellent functional group compatibility.

Key Points

  • The iron-catalyzed ATRA reaction efficiently produces 1,3-dibromo compounds under mild conditions.
  • This method demonstrates broad substrate scope and excellent atom economy, enabling diverse applications.
  • Using visible light, the protocol shows remarkable versatility and functional group compatibility in alkenes.
  • The resulting dibromo compounds serve as versatile synthetic building blocks for further transformations.

Cite This Study

Yan et al. (2025) studied this question.

synapsesocial.com/papers/68af4754ad7bf08b1ead3fbfhttps://doi.org/10.1002/anie.202511486
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