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January 1, 2025Dalton TransactionsOpen Access

Structural diversities and magnetic properties of azido- and dicyanamido-bridged coordination polymers with 4,5-diphenylimidazole as terminal ligand

Evangelia-Spyridoula Fotopoulou Nikos Panagiotou Anastasios J. Tasiopoulos Mark M. Turnbull Spyros P. Perlepes V. Nastopoulos

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Key Points

Azido- and dicyanamido-bridged coordination polymers exhibit unique magnetic properties, enhancing material functionality.
The complexes synthesized showed significant variation in structural diversity due to the presence of pseudohalides.
Characterization methods revealed the intricate interplay of imidazole ligands in the copper(II) complexes.
Finding alternative bridging ligands, like pseudohalides, may enable novel advancements in supramolecular chemistry.

Implication

Synthesis of azido- and dicyanamido-bridged coordination polymers reveals the role of pseudohalides in structural diversity, suggesting new pathways in material design.

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Cite This Study

Fotopoulou et al. (2025) studied this question.

synapsesocial.com/papers/68af4766ad7bf08b1ead4ab4 https://doi.org/10.1039/d5dt01389e

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