Observational analysis correlates electronic properties with branching density in polyethylene, suggesting catalyst tuning may improve outcomes.
Electronic tuning of the para -R group of the Ni precatalyst allows a means to regulate the branching density and the M w of the PE. The E 1/2 value of the precatalyst has been used as a quantitative descriptor of this electronic effect.
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Zeng et al. (2025) studied this question.
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