Palladium-catalyzed carbonylation produces fluoroalkylated allenyl primary amides with high selectivity, indicating diverse applications.
A palladium-catalyzed difunctional fluoroalkylative carbonylation of 1,3-enynes with fluoroalkyl halides and ammonium iodide has been developed, providing rapid access to fluoroalkylated allenyl primary amides with a broad substrate scope, high chemo- and regioselectivity, and good functional group tolerance.
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Kuai et al. (2025) studied this question.
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