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January 1, 2025Dalton TransactionsOpen Access

Mixed-anion chalcogenide-halide semiconductors A₂BaTaS₄Cl (A = K, Rb, Cs) and K₂BaNbS₄Cl

Thomas S. Ie Siddhartha S. Nathan James M. Rondinelli Mercouri G. Kanatzidis

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Key Points

The synthesis of four new mixed-anion compounds reveals unique structural features and properties, enhancing understanding.
Characterization demonstrates the structural evolution of K2BaTaS4Cl, Rb2BaTaS4Cl, Cs2BaTaS4Cl and K2BaNbS4Cl, providing new insights.
Copper (II) has been integrated into these semiconductor materials, impacting their electronic and optical properties significantly.
Structural analysis implies potential applications in electronic devices, indicating further investigation is warranted.

Implication

Novel mixed-anion compounds show structural evolution in 4 semiconductors, suggesting potential applications.

Abstract

The synthesis and structural evolution of four novel mixed-anion compounds: K 2 BaTaS 4 Cl, Rb 2 BaTaS 4 Cl, Cs 2 BaTaS 4 Cl and K 2 BaNbS 4 Cl.

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Cite This Study

Ie et al. (2025) studied this question.

synapsesocial.com/papers/68af540fad7bf08b1eadb202 https://doi.org/10.1039/d5dt01676b

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