What question did this study set out to answer?

The aim is to synthesize and characterize two mixed-anion chalcohalides, examining their structural and thermal properties.

April 18, 2026Dalton Transactions

Layered Mixed-Anion Chalcohalides Pb4Sb4Q9Cl2 (Q = S, Se): Puckered 2D Frameworks, Indirect Band Gaps, and Low Thermal Conductivity

View Full Paper

Ask AI

Bookmark

The aim is to synthesize and characterize two mixed-anion chalcohalides, examining their structural and thermal properties.
Synthesized Pb4Sb4S9Cl2 and Pb4Sb4Se9Cl2 using solid-state reactions.
Characterized structures using crystallographic analysis in the orthorhombic space group Pbam.
Measured thermal conductivity and band gap properties.
Achieved successful synthesis of two distinct mixed-anion chalcohalides.
Identified puckered two-dimensional frameworks in both compounds.
Observed indirect band gaps and low thermal conductivity values.

Implication

This research synthesizes mixed-anion chalcohalides and reveals their properties, suggesting potential applications in electronics.

Abstract

Two mixed-anion chalcohalides, Pb4Sb4S9Cl2 and Pb4Sb4Se9Cl2, were synthesized by solid-state reactions and crystallize in the orthorhombic space group Pbam (No. 55). Their structures consist of puckered two-dimensional 〖(_∞^2)[Pb_4 Sb_4 Q_9...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Huang et al. (2026) studied this question.

synapsesocial.com/papers/69e3203440886becb653f55e https://doi.org/10.1039/d6dt00115g

View Full Paper

Ask AI

Bookmark

Implication

This research synthesizes mixed-anion chalcohalides and reveals their properties, suggesting potential applications in electronics.

Layered Mixed-Anion Chalcohalides Pb4Sb4Q9Cl2 (Q = S, Se): Puckered 2D Frameworks, Indirect Band Gaps, and Low Thermal Conductivity

Key Points

Implication

Abstract

Discussion

Cite This Study

Layered Mixed-Anion Chalcohalides Pb4Sb4Q9Cl2 (Q = S, Se): Puckered 2D Frameworks, Indirect Band Gaps, and Low Thermal Conductivity

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading