Synapse
⌘+K
Synapse
PulseExploreClubsResearchersJournals
Instagram
HomeClubsExplore
August 21, 2025Angewandte Chemie

Quest for Luminescent Low‐Spin Chromium(I) Complexes with Doublet Metal‐to‐Ligand Charge‐Transfer Excited States

View Full Paper
Ask AI
Bookmark
Share

Authors

MYMengwei YueWTWai‐Pong ToYZYifan Zhao

Discussion

Loading...

Member takes

Overview

Paramagnetic chromium complexes exhibit distinct metal-to-ligand charge-transfer states, highlighting diversity in emissive properties.

Key Points

  • Excited state lifetimes for chromium complexes are in the tens of picoseconds, emphasizing their rapid dynamics.
  • Emission peaks at 568 nm and 525 nm indicate significant luminescence, setting these complexes apart from iron counterparts.
  • The study combines structural, spectroscopic, and theoretical approaches to understand these chromium complexes' behavior.
  • Results suggest that chromium(I) complexes with 2 MLCT states offer new insights into earth-abundant 3d transition metal emissive properties.

Cite This Study

Yue et al. (2025) studied this question.

synapsesocial.com/papers/68af55c6ad7bf08b1eadbe82https://doi.org/10.1002/ange.202509601
View Full Paper
Ask AI
Bookmark
Share

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Quest for Luminescent Low‐Spin Chromium(I) Complexes with Doublet Metal‐to‐Ligand Charge‐Transfer Excited States2025
  2. 2Energy Storage in the Outer Coordination Sphere of a Chromium(0) Complex Enhances Photophysical and Photochemical Properties2026 · 1 citations
  3. 3Ferromagnetically Coupled Chromium(III) Dimer Shows Luminescence and Sensitizes Photon Upconversion2024 · 8 citations
  4. 4Controlling the Photophysical Properties of a Series of Isostructural d<sup>6</sup> Complexes Based on Cr<sup>0</sup>, Mn<sup>I</sup>, and Fe<sup>II</sup>2024 · 39 citations
  5. 5Electrochemiluminescence of a First‐Row d<sup>6</sup> Transition Metal Complex2024