Surface-Coated Nano-Sized Aluminum Powder’s Applications in Explosives and Propellants: A Review

Aluminum powder has the advantages of high calorific value, high density and convenient source, and is a commonly used metal fuel in the explosives and propellants industry. Nanometer aluminum powder (nAl) has higher reactivity and higher reaction completeness than micron aluminum powder (μAl), which can improve the energy performance of mixed explosives and the burning rate of propellant. However, nAl has some disadvantages, such as easy oxidation and deterioration of the preparation process, which seriously affect its application efficiency. In order to improve these shortcomings, suitable surface coating treatment is needed. The effects of surface coating on the characteristics of nAl and on the energy and safety of explosives are summarized in this paper. The results show that surface coating of nAl can not only improve the compatibility between nAl and energetic materials, reduce the hygroscopicity of energetic composites, mitigate the easy oxidation of nAl, and protect the preparation process, but also improve the energy performance of explosives and the burning rate of propellant, increase the reaction characteristics of energetic mixtures, and reduce the mechanical sensitivity of those mixtures. In addition, the surface coating modification of nAl can obviously reduce the agglomeration of condensed-phase combustion products, thus reducing the loss of propulsion efficiency caused by agglomeration. This study is expected to provide reference for the surface coating of nAl and its application in explosives.