Synthesis, Properties, and Chemoselective Reactions of an AlH–BH Functional Group

Mark R. Crimmin; Wenbang Yang; Andrew J. P. White

doi:10.1039/d5sc05133a

January 1, 2025Chemical ScienceOpen Access

Synthesis, Properties, and Chemoselective Reactions of an AlH–BH Functional Group

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Key Points

A novel alumaborane compound containing an AlH–BH functional group was synthesized.
This compound was formed through a reaction involving an aluminium(I) complex and boron dihydride.
The research emphasizes the unique properties and potential applications of the AlH–BH functional group.
Understanding these properties may enable new chemoselective reactions in organic synthesis.

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Implication

This research demonstrates the synthesis of a new alumaborane compound, highlighting its properties and chemoselective reactions.

Abstract

A new alumaborane compound containing a {AlH–BH} functional group has been prepared by reaction of the aluminium(I) complex [{(ArCMeN) 2 CH}Al] (Ar = 2,6-i-Pr 2 C 6 H 3 ) with a boron dihydride species supported by an...

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Crimmin et al. (2025) studied this question.

synapsesocial.com/papers/68af5bafad7bf08b1eadf033 https://doi.org/10.1039/d5sc05133a

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Synthesis, Properties, and Chemoselective Reactions of an AlH–BH Functional Group

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Synthesis, Properties, and Chemoselective Reactions of an AlH–BH Functional Group

Key Points

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Abstract

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