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This is a In Vitro Study study.

Radical 1,2-Boron Shift-Enabled Synthesis of β-Thioalkylboronic Esters from β-Boryl NHPI Esters

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Novel protocol enables synthesis of β-thioalkylboronic esters from NHPI esters, highlighting diverse applications.

The method allows for the efficient synthesis of β-thioalkylboronic esters, expanding synthetic applications in organic chemistry.
Key evidence shows a radical-mediated 1,2-boron migration pathway involved in the reaction.
The approach utilizes decarboxylative functionalization techniques for enhanced versatility and a broad substrate scope.
This methodology diversifies boron migration chemistry, emphasizing new pathways for constructing C(sp3)–S bonds.

LIN et al. (2025) studied this question.

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