Two-Coordinate Co and Ni Complexes of a Bulky Imidazolin-2-iminato Ligand and Facile Synthesis of Heterobimetallic Complexes

Yu‐Hsuan Chen; Guanwen Chen; Yeongyeon Lee; Hsin‐Kuan Liu; Chun‐Yi Lin

doi:10.1039/d5dt01455g

January 1, 2025Dalton Transactions

Two-Coordinate Co and Ni Complexes of a Bulky Imidazolin-2-iminato Ligand and Facile Synthesis of Heterobimetallic Complexes

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Key Points

Synthesis of two-coordinate cobalt and nickel complexes was confirmed through single-crystal X-ray diffraction.
Homoleptic complexes were achieved using the sterically hindered NImDipp ligand, demonstrating stability.
The study outlines a straightforward method for creating heterobimetallic complexes using these metal complexes.
Single-crystal X-ray diffraction validates the presence of two-coordinate complexes in the synthesized materials.

Implication

Synthesis reveals new two-coordinate cobalt and nickel complexes, suggesting pathways for heterobimetallic formulation.

Abstract

We report the synthesis of homoleptic two-coordinate Co and Ni complexes supported by a sterically hindered NImDipp ligand (1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato). Their formulation as two-coordinate complexes was verified by single-crystal X-ray diffraction...

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Cite This Study

Chen et al. (2025) studied this question.

synapsesocial.com/papers/68bb3d552b87ece8dc956173 https://doi.org/10.1039/d5dt01455g

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Two-Coordinate Co and Ni Complexes of a Bulky Imidazolin-2-iminato Ligand and Facile Synthesis of Heterobimetallic Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

Two-Coordinate Co and Ni Complexes of a Bulky Imidazolin-2-iminato Ligand and Facile Synthesis of Heterobimetallic Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

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