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Dimension-Tunable Supramolecular Organic Frameworks with Chiral Pore Channels for Selective Guest Encapsulation and Enhanced Circularly Polarized Luminescence

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This research demonstrates enhanced circularly polarized luminescence in chiral pore channels, indicating potential in selective guest encapsulation.

The chiral SOFs show enhanced circularly polarized luminescence with a dissymmetry factor of 1.6 × 10-2.
Fabrication involves vapor diffusion and antisolvent self-assembly methods to create dimension-tunable structures.
Characterizations include N2 adsorption-desorption, high-resolution transmission electron microscopy, and density functional theory calculations.
Findings deepen understanding of chirality transfer and selective adsorption in porous materials.

Li et al. (2025) studied this question.

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This research demonstrates enhanced circularly polarized luminescence in chiral pore channels, indicating potential in selective guest encapsulation.