Establishing σ-hole tetrel bonds by hemidirected lead(II) phosphonodithioates

Pretam Kumar; Rosa M. Gomila; Antonio Frontera; Sushil Pandey

doi:10.1039/d5ce00611b

January 1, 2025CrystEngComm

Establishing σ-hole tetrel bonds by hemidirected lead(II) phosphonodithioates

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Key Points

Hemidirected lead(II) centres effectively form σ-hole tetrel bonds with various electron-rich atoms, expanding the understanding of these interactions.
Utilizing Lawesson's reagent, arylphosphonodithioates were synthesized, revealing significant bonding characteristics based on electron density.
The research employed a systematic approach to investigate the interactions of lead(II) phosphonodithioates with electron donors, adding to the chemistry of σ-hole interactions.
This study highlights potential applications in material science and molecular design, suggesting innovative pathways for utilizing tetrel bonds.

Implication

This study demonstrates σ-hole tetrel bonds in lead(II) complexes with electron-rich atoms, suggesting new bonding interactions.

Abstract

This study explores the ability of hemidirected lead(II) centres to form σ-hole tetrel bonds (TtBs) with electron-rich atoms. Lawesson’s reagent was used to produce arylphosphonodithioates and their associated lead(II) complex...

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Cite This Study

Kumar et al. (2025) studied this question.

synapsesocial.com/papers/68bb42212b87ece8dc958c17 https://doi.org/10.1039/d5ce00611b

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Establishing σ-hole tetrel bonds by hemidirected lead(II) phosphonodithioates

Key Points

Implication

Abstract

Discussion

Cite This Study

Establishing σ-hole tetrel bonds by hemidirected lead(II) phosphonodithioates

Key Points

Implication

Abstract

Discussion

Cite This Study

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