Crystal structures of hydroxylamine and a 15-crown-5 hydroxylaminosolvate: first observation of a cyclic hydroxylamine dimer (NH₂OH)₂

Mher A. Navasardyan; Danila R. Chernyavskiy; Mikhail Vener

doi:10.1039/d6ce00321d

January 1, 2026CrystEngComm

Crystal structures of hydroxylamine and a 15-crown-5 hydroxylaminosolvate: first observation of a cyclic hydroxylamine dimer (NH₂OH)₂

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Key Points

The aim is to determine the crystal structure of hydroxylamine and its solvated form using diffraction data.
Utilized modern diffraction techniques to analyze the crystal structure
Investigated both neat hydroxylamine and its solvated form with 15-crown-5
Successfully determined the first crystal structure of neat hydroxylamine
Identified a cyclic hydroxylamine dimer in the crystal structure

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Implication

Structural analysis reveals cyclic hydroxylamine dimer formation in hydroxylamine and solvated forms.

Abstract

The crystal structure of neat hydroxylamine (I) has been determined for the first time using modern diffraction data, and the 15 crown 5 hydroxylaminosolvate (II) has been obtained. All hydrogen...

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Navasardyan et al. (2026) studied this question.

synapsesocial.com/papers/6a36300ddb0793dc1a53761c https://doi.org/10.1039/d6ce00321d

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Crystal structures of hydroxylamine and a 15-crown-5 hydroxylaminosolvate: first observation of a cyclic hydroxylamine dimer (NH₂OH)₂

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Crystal structures of hydroxylamine and a 15-crown-5 hydroxylaminosolvate: first observation of a cyclic hydroxylamine dimer (NH₂OH)₂

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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