Cyclam(OH)₄ as an adaptable co-former for co-crystals with carboxylic acids and phenols

Vladislav Lesnikov; Alexey Yu. Sukhorukov

doi:10.1039/d6ce00350h

January 1, 2026CrystEngComm

Cyclam(OH)₄ as an adaptable co-former for co-crystals with carboxylic acids and phenols

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Key Points

This research aims to explore the potential of cyclam(OH)₄ as a co-former in the creation of co-crystals with carboxylic acids and phenols.
Used co-crystallization techniques to investigate the formation of co-crystals.
Analyzed the hydrogen bonding interactions between cyclam(OH)₄ and various acidic compounds.
Evaluated the structural properties and stability of the resultant co-crystals.
Successfully obtained multiple co-crystals with carboxylic acids and phenols.
Demonstrated favorable hydrogen bonding interactions, enhancing crystallization efficiency.
Showed potential for broader application of hydroxylamines in supramolecular chemistry.

Implication

Demonstrates co-crystallization of cyclam(OH)₄ with carboxylic acids and phenols, indicating versatile applications in supramolecular chemistry.

Abstract

While (macro)cyclic amines are widely used as co-formers in the design of supramolecular hydrogen-bonded crystalline networks, organic hydroxylamines remain almost unexplored in this context. Here, co-crystallization of the tetra-N-hydroxylated cyclam...

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Cite This Study

Lesnikov et al. (2026) studied this question.

synapsesocial.com/papers/6a363040db0793dc1a53770d https://doi.org/10.1039/d6ce00350h

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Cyclam(OH)₄ as an adaptable co-former for co-crystals with carboxylic acids and phenols

Key Points

Implication

Abstract

Discussion

Cite This Study

Cyclam(OH)₄ as an adaptable co-former for co-crystals with carboxylic acids and phenols

Key Points

Implication

Abstract

Discussion

Cite This Study

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