Trends in benzene inverse sandwich complexes of the alkaline-earth metals Mg, Ca, Sr and Ba

Q: What type of study is this?

This is a Mechanochemical reduction study.

Dawid Jędrzkiewicz; Michael Morasch; Oliver P. E. Townrow; Bastian Rösch; Jens Langer; Zachary Mathe; Sjoerd Harder

doi:10.1039/d5sc05373k

January 1, 2025Chemical ScienceOpen Access

Trends in benzene inverse sandwich complexes of the alkaline-earth metals Mg, Ca, Sr and Ba

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Key Points

First barium inverse sandwich complexes containing benzene dianion achieved high yields of 54%.
Mechanochemical reduction effectively utilized β-diketiminate barium iodide precursors in the reaction.
This study highlights the emerging interest in synthesizing inverse sandwich complexes from alkaline-earth metals.
The findings may lead to innovative pathways in the chemistry of benzene complexes and metal interactions.

Implication

Mechanochemical reduction produced barium inverse sandwich complexes with benzene dianion, suggesting new reactions in alkaline-earth chemistry.

Abstract

Mechanochemical reduction of β-diketiminate (BDI) barium iodide precursors with K/KI resulted in the first barium inverse sandwich complexes containing the benzene dianion in yields of up to 54%. This most...

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Cite This Study

Jędrzkiewicz et al. (2025) studied this question.

synapsesocial.com/papers/68bb42212b87ece8dc958c32 https://doi.org/10.1039/d5sc05373k

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Trends in benzene inverse sandwich complexes of the alkaline-earth metals Mg, Ca, Sr and Ba

Key Points

Implication

Abstract

Discussion

Cite This Study

Trends in benzene inverse sandwich complexes of the alkaline-earth metals Mg, Ca, Sr and Ba

Key Points

Implication

Abstract

Discussion

Cite This Study

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