This analysis determines kinetic parameters of thermal decomposition in nitrocellulose systems, highlighting method sensitivity.
This study presents the results of determining the kinetic parameters of the decomposition process of system Nitrocellulose-Cellulose-Trinitrotoluene. The kinetic parameters were determined based on differential scanning calorimetry (DSC) data using the Kissinger and Ozawa methods of NC in the samples of NC, NC-Cellulose, NC-Trinitrotoluene dissolved in solution, molten NC-Trinitrotoluene, NC-Cellulose-Trinitrotoluene, NC-Cellulose-Trinitrotoluene-DPA, NC-Cellulose-Trinitrotoluene-Centralite No. 1, NC-Cellulose-Trinitrotoluene-Centralite No. 2. The degree of thermal decomposition of the samples of NC-Cellulose-Trinitrotoluene containing chemical stabilizers such as DPA, Centralite No. 1, Centralite No. 2 was evaluated by measuring the gas pressure over time of the decomposition products.
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Phạm Văn Khương (2025) studied this question.
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