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September 10, 2025Open Access

C6-ROMP: Structure-Guided Monomer Design for Chemically Recyclable Polymers

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This research reveals how monomer design enhances romp polymerization in cyclohexene, indicating improved recyclability.

Monomer design enhances romp efficiency through adaptive ring strain modulation with five-membered heterocycles.
An ethenolysis ring strain energy threshold of about 4.3 kcal/mol is crucial for effective polymerization.
Thermodynamic analysis shows that substituent flexibility significantly affects depolymerization efficiency and temperature.
The developed polymers exhibit a broad range of thermal properties and show potential for sustainable recycling.

Choi et al. (2025) studied this question.

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