Zn-cycloalkyldicarboxylate 2D-Coordination Polymers bearing 4,4'-trimethylenebipyridine: Crystal structures, Solid state CPMAS 13C NMR Structural Correlations and Luminescent Sensing of Ethanol

Jonathan Jaramillo‐García; Víctor Sánchez‐Mendieta; Luis D. Rosales‐Vázquez; Raúl A. Morales‐Luckie; Diego Martínez‐Otero; Juan Manuel Germán-Acacio; Cristian Pinzón-Vanegas; Juan Pablo León-Gómez; Alejandro Dorazco‐González

doi:10.1039/d5dt01490e

January 1, 2025Dalton Transactions

Zn-cycloalkyldicarboxylate 2D-Coordination Polymers bearing 4,4'-trimethylenebipyridine: Crystal structures, Solid state CPMAS 13C NMR Structural Correlations and Luminescent Sensing of Ethanol

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Key Points

Luminescent sensing of ethanol was achieved using three unique coordination polymers synthesized from zinc.
The crystal structures of these polymers revealed significant insights into their solid-state NMR properties.
The self-assembly methods utilized flexible ligands, which contributed to the unique properties of the resulting coordination polymers.
This research demonstrates potential applications in sensor technology through coordination chemistry and structural analysis.

Implication

Self-assembly creates flexible coordination polymers, highlighting solid-state structural correlations and sensing capabilities.

Abstract

Self-assembly reactions of Zn(II) with cyclobutane-1,1'-dicarboxylate (cbdc) or cyclohexane-1,1´-dicarboxylate (chdc) and 4,4'-trimethylenebipyridine (tmbp) generated three flexible mixed-ligands coordination polymers: {[Zn(cbdc)(tmbp)]·(H2O)}n, 1; {[Zn(H2O)(cbdc)(tmbp)]}n, 2; and {[Zn(chdc)(tmbp)]·H2O}n, 3. These crystalline polymers were...

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Cite This Study

Jaramillo‐García et al. (2025) studied this question.

synapsesocial.com/papers/68c188509b7b07f3a06122da https://doi.org/10.1039/d5dt01490e

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Zn-cycloalkyldicarboxylate 2D-Coordination Polymers bearing 4,4'-trimethylenebipyridine: Crystal structures, Solid state CPMAS 13C NMR Structural Correlations and Luminescent Sensing of Ethanol

Key Points

Implication

Abstract

Discussion

Cite This Study

Zn-cycloalkyldicarboxylate 2D-Coordination Polymers bearing 4,4'-trimethylenebipyridine: Crystal structures, Solid state CPMAS 13C NMR Structural Correlations and Luminescent Sensing of Ethanol

Key Points

Implication

Abstract

Discussion

Cite This Study

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