New method demonstrates N-O coupling yielding O-imido oximes from benzyl azides and N-hydroxyimides, suggesting novel applications in organic synthesis.
Electrochemically induced synthesis of O-imido oximes from benzyl azides and N-hydroxyimides via N-O coupling has been discovered. The developed approach reveals a new role of benzyl azides in the practice of organic synthesis as precursors of iminyl radicals for intermolecular coupling reactions. The method is applicable to a wide range on benzyl azides and N-hydroxyimides, and O-imido oximes are obtained in yields up to 94%.
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Paveliev et al. (2025) studied this question.
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