Ba₃Al₂B₁₂O₂₄: a beryllium-free member of the Sr₂Be₂B₂O₇ family with a ²∞[B₁₂Al₂O₂₈] double-layered structure

Xiaorong Liu; Hongping Wu; Zhanggui Hu; Jiyang Wang; Yicheng Wu; Hongwei Yu

doi:10.1039/d5sc03854e

January 1, 2025Chemical ScienceOpen Access

Ba₃Al₂B₁₂O₂₄: a beryllium-free member of the Sr₂Be₂B₂O₇ family with a ²∞[B₁₂Al₂O₂₈] double-layered structure

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Key Points

The synthesized Ba3Al2B12O24 demonstrates significant SHG response, suitable for optical applications.
Birefringence values align with desired optical characteristics, enhancing its applicability in photonics.
The unique double-layered structure contributes to the material's performance balance, indicating structural significance.
This beryllium-free compound represents a notable advancement in the Sr2Be2B2O7 family for optoelectronic materials.

Implication

Synthesis achieves optimal performance balance in Ba3Al2B12O24, indicating favorable birefringence and SHG response.

Abstract

A new Sr 2 Be 2 B 2 O 7 -like aluminoborate Ba 3 Al 2 B 12 O 24 was synthesized, satisfying performance balance between large SHG response, a short cutoff edge, and appropriate birefringence.

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Cite This Study

Liu et al. (2025) studied this question.

synapsesocial.com/papers/68c18c019b7b07f3a06145cf https://doi.org/10.1039/d5sc03854e

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Ba₃Al₂B₁₂O₂₄: a beryllium-free member of the Sr₂Be₂B₂O₇ family with a ²∞[B₁₂Al₂O₂₈] double-layered structure

Key Points

Implication

Abstract

Discussion

Cite This Study

Ba₃Al₂B₁₂O₂₄: a beryllium-free member of the Sr₂Be₂B₂O₇ family with a ²∞[B₁₂Al₂O₂₈] double-layered structure

Key Points

Implication

Abstract

Discussion

Cite This Study

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