Synthesis of rotaxane ligands enhances electrocatalytic activity for O2 reduction, suggesting a novel approach.
We developed tridentate rotaxane ligands to stabilise a dynamic Cu(I) centre with an empty coordination site for O2 reduction. Electrocatalytic activity and selectivity can be controlled by the interlocking tightness through varying the macrocycle size, a feat traditionally inaccessible by non-interlocked analogues.
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Zhang et al. (2025) studied this question.
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