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This research reports the synthesis of phenalenyl complexes containing C=Re=C units, suggesting unique metallaaromatic properties.
Metallaaromatics are attractive due to their special structures and properties. In this work, the first metalla-phenalenyl complexes containing C=Re=C units were obtained from ReCl3(PMePh2)3 and 1,8-diethynylnaphthalene compounds. The delocalized rhenaphenalenyl...
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Li et al. (2025) studied this question.
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