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September 10, 2025Inorganic ChemistryOpen Access

Phenylpyridine-Based Boron Azides: Tuning Reactivity and Accessing Fluorescent Triazoles

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Authors

KŠKarel ŠkochCzech Academy of Sciences, Institute of Inorganic ChemistryMBMichaela BuzikováCzech Academy of Sciences, Institute of Inorganic ChemistryDHDrahomı́r HnykEötvös Loránd University

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Overview

Research shows weak electrophilic character of boron azides, indicating potential for UV-A fluorescence applications.

Key Points

  • Boron azides exhibit notable thermal stability with decomposition temperatures exceeding 170 °C in solid state.
  • Reactivity studies reveal weak electrophilic nature, shown by reluctance in Staudinger-type reactions and high activation barriers.
  • Computational analysis corroborates experimental data, providing insights into orbital interactions during cycloadditions.
  • Selected boron-triazole products demonstrate UV-A fluorescence with high quantum yields up to 0.74 in solution.

Cite This Study

Škoch et al. (2025) studied this question.

synapsesocial.com/papers/68c192459b7b07f3a0616628https://doi.org/10.1021/acs.inorgchem.5c03363
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