Streamlined synthesis of meta- or para-substituted triphenylamine[3]arenes and their hierarchical assembly into polyhedral cages

Wangjian Fang; Xin Li; Audrey Nathania; Yimin Zhang; Guoqiang Jiang; Andrew C.‐H. Sue

doi:10.1039/d5qo01089f

January 1, 2025Organic Chemistry Frontiers

Streamlined synthesis of meta- or para-substituted triphenylamine[3]arenes and their hierarchical assembly into polyhedral cages

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Key Points

The streamlined synthesis effectively produces novel triphenylamine[3]arenes for advanced applications.
Key findings indicate successful hierarchical assembly into stable polyhedral cages during experiments.
The method leverages both meta and para-substituted variants to enhance the structural properties of TPA[3]s.
Implications include broadening the scope of macrocyclic scaffolds in supramolecular chemistry applications.

Implication

This synthesis reveals meta and para-substituted triphenylamine[3]arenes, suggesting new pathways in supramolecular chemistry.

Abstract

Triphenylamine[3]arenes (TPA[3]s) are a novel class of macrocyclic scaffolds with remarkable potential in supramolecular chemistry. In this study, we present a streamlined synthesis of TPA[3]s featuring meta or para-substituted bromophenyl...

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Cite This Study

Fang et al. (2025) studied this question.

synapsesocial.com/papers/68c192459b7b07f3a06166cb https://doi.org/10.1039/d5qo01089f

View Full Paper

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Streamlined synthesis of meta- or para-substituted triphenylamine[3]arenes and their hierarchical assembly into polyhedral cages

Key Points

Implication

Abstract

Discussion

Cite This Study

Streamlined synthesis of meta- or para-substituted triphenylamine[3]arenes and their hierarchical assembly into polyhedral cages

Key Points

Implication

Abstract

Discussion

Cite This Study

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