Remarkable Coordination Variability of P,C,P-pincer ligand in Organotin(IV) Compounds - A Promising Message for Other p-Block Elements.

Richard Chlebík; Erik Kertész; Milan Erben; Aleš Růžička; Roman Jambor; Zoltán Benkő; Libor Dostál

doi:10.1039/d5dt01873k

January 1, 2025Dalton TransactionsOpen Access

Remarkable Coordination Variability of P,C,P-pincer ligand in Organotin(IV) Compounds - A Promising Message for Other p-Block Elements.

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Key Points

The study reveals notable coordination variability in organotin(IV) compounds involving a pincer ligand, enhancing our understanding of metal-ligand interactions.
Analysis of compounds like ArSnPh2Cl, ArSnPhCl2, and ArSnCl3 shows varying coordination modes, contributing to the field of organometallic chemistry.
The evaluation used advanced coordination chemistry techniques to highlight how subtle changes in ligand structure can affect compound properties.
This work implies potential applications of pincer ligands in designing new organotin complexes and exploring their properties further.

Implication

Examining coordination properties of a pincer ligand in organotin compounds suggests novel applications for p-block elements.

Abstract

The coordination properties of the P,C,P-pincer ligand (Ar = 2,6-(tBu2PO)2C6H3) to organotin(IV) compounds were examined. For this purpose, a set of neutral compounds including ArSnPh2Cl (1), ArSnPhCl2 (2) and ArSnCl3...

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Cite This Study

Chlebík et al. (2025) studied this question.

synapsesocial.com/papers/68c198cd9b7b07f3a061ad0b https://doi.org/10.1039/d5dt01873k

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Remarkable Coordination Variability of P,C,P-pincer ligand in Organotin(IV) Compounds - A Promising Message for Other p-Block Elements.

Key Points

Implication

Abstract

Discussion

Cite This Study

Remarkable Coordination Variability of P,C,P-pincer ligand in Organotin(IV) Compounds - A Promising Message for Other p-Block Elements.

Key Points

Implication

Abstract

Discussion

Cite This Study

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