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September 10, 2025Organic & Biomolecular Chemistry

Recent Advances in Photoinduced Amidyl Radical-Mediated Remote C(sp3)–H Activation via 1,5-Hydrogen Atom Transfer

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The study highlights significant advancements in functionalizing unactivated C(sp³)–H bonds, improving chemical diversity in organic synthesis.
Recent techniques utilize amidyl radicals and 1,5-hydrogen atom transfer for efficient activation of otherwise inert C-H bonds.
By focusing on remote activation methods, the findings suggest new possibilities for broad applications in organic chemistry.
This approach may enable chemists to explore complex molecules more effectively, streamlining synthetic pathways.

Implication

This review demonstrates advancements in remote activation of unactivated C(sp³)–H bonds using amidyl radicals, highlighting broader chemical diversification.

Abstract

C-H bonds are widely present in organic molecules and play a crucial role in chemical diversification. Among them, the functionalization of unactivated C(sp³)-H bonds is highly challenging. The 1,5-hydrogen atom...

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Cite This Study

Liao et al. (2025) studied this question.

synapsesocial.com/papers/68c198cd9b7b07f3a061ae30 https://doi.org/10.1039/d5ob01197c

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Implication

This review demonstrates advancements in remote activation of unactivated C(sp³)–H bonds using amidyl radicals, highlighting broader chemical diversification.

Recent Advances in Photoinduced Amidyl Radical-Mediated Remote C(sp3)–H Activation via 1,5-Hydrogen Atom Transfer

Key Points

Implication

Abstract

Discussion

Cite This Study

Recent Advances in Photoinduced Amidyl Radical-Mediated Remote C(sp3)–H Activation via 1,5-Hydrogen Atom Transfer

Key Points

Implication

Abstract

Discussion

Cite This Study

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