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This is a DFT calculations study (also classified as: Cyclic Voltammetry, NMR, HR-MS, Electron Spin Resonance).

September 10, 2025ACS OmegaOpen Access

Dimer of the DPPH Stable Radical

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Dimerization of DPPH radical was achieved through an alternative synthesis, leading to new structural insights.
Oxidation of the DPPH-dimer generated a diradical that retained properties similar to the original DPPH radical.
Analyses like NMR and electron spin resonance confirmed the structures and characteristics of the synthesized compounds.
DFT calculations indicated an open-shell singlet ground state with significant diradical character.

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Research reveals novel dimer of DPPH radical with notable electrochemical and magnetic properties, suggesting potential applications.

Dobre et al. (2025) studied this question.

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