Promoting Zn²⁺ Interfacial Transfer and (002)‐Textured Zn Deposition via a Thin AlF₃ Layer for Stable Zn Electrode in Aqueous Battery

Suppressing zinc (Zn) dendrite and corrosion is a crucial challenge for aqueous Zn batteries (AZBs). An aluminum (Al) protective layer can regulate Zn deposition by enhancing Zn 2+ interfacial transfer through the Zn–Al alloy, which however suffers from the sensitive passivation by Al 2 O 3 . While employing a thick Al layer may preserve the Zn protective ability despite the surface passivation, it inevitably compromises the energy density of the battery accordingly. Herein, a thin AlF 3 layer (<1 µm) is proposed to address these issues, where the strong Al─F bonds endow the thin layer with a high stability against the surface passivation. Meanwhile promoted Zn 2+ interfacial transfer on the AlF 3 surface is revealed by experimental and modeling approaches. Furthermore, the AlF 3 layer favors a (002)‐textured Zn deposition owing to the low interfacial energy between Zn(002)/AlF 3 (002) facets, leading to uniform and corrosion‐resistant Zn deposits. Consequently, a high coulombic efficiency of 99.9% is achieved for Zn cycling at 2 mA cm −2 over 8000 cycles, and the Zn‖I 2 full cell achieves a high capacity retention of 92.1% after 7500 cycles. This work provides valuable insights into the construction of thin protective layer for stable Zn electrode in AZBs.