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Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II)

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X-ray diffraction reveals distinct structures of triphenylsulfonium salts in monoclinic space groups, indicating unique geometry.

These three triphenylsulfonium salts exhibit unique crystal structures, with distinct bond lengths.
The salts crystallize in monoclinic space groups, with different distorted geometries observed.
Hirshfeld surface analysis highlights significant interactions in the crystal environments of these compounds.
Involving manganese, iron, and cobalt, the complexes demonstrate varied cation arrangements and interactions.

Callaway et al. (2025) studied this question.

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