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Carboxylate-Directed Self-Assembly of Mo2O42+ Units for Enhanced Proton Conduction

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New polyoxomolybdate complexes show improved proton conduction, highlighting the role of hydrogen-bonding networks.

Complexes 1-3 achieved significant proton conductivities up to 3.52 × 10-2 S cm-1 at high humidity and temperature.
Synthesis involved novel condensation reactions of carboxylic acid ligands and [Mo2O4(H2O)6]2+ precursor, creating stable structures.
Characterization techniques, including single-crystal X-ray diffraction, defined the structure and highlighted conduction pathways in complexes.
Extensive hydrogen-bonding networks were crucial for facilitating proton transfer and enhancing conductivity properties.

Liu et al. (2025) studied this question.

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View Full Paper

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Authors

New polyoxomolybdate complexes show improved proton conduction, highlighting the role of hydrogen-bonding networks.

Complexes 1-3 achieved significant proton conductivities up to 3.52 × 10-2 S cm-1 at high humidity and temperature.
Synthesis involved novel condensation reactions of carboxylic acid ligands and [Mo2O4(H2O)6]2+ precursor, creating stable structures.
Characterization techniques, including single-crystal X-ray diffraction, defined the structure and highlighted conduction pathways in complexes.
Extensive hydrogen-bonding networks were crucial for facilitating proton transfer and enhancing conductivity properties.

Liu et al. (2025) studied this question.

View Full Paper

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